Walk down a supermarket aisle and the packets sound so reassuring: “High protein”, “no added trans fat”, “no added sugar”, little green ticks, heart icons, smiling grains.
But the chemistry inside those boxes does not care about slogans. It cares about fatty acid chains, amino acid patterns, preservative reactions, and how those interact with your insulin, gut barrier, and brain.
Labels tell a marketing story. Your mitochondria read a chemical one.
1. Hidden Fat: When Food Doesn’t Look Oily but Is
Fat is easy to see in a block of butter or a bottle of oil. It’s much less obvious when it’s:
- soaked into crisps and oven chips,
- woven into pastries, pies, garlic bread,
- spread invisibly through “just add water” mixes,
- emulsified into sauces, coffee creamers, shakes.
The trick is simple: take a plant like the oil palm, strip away the fibre, pigments, vitamins and antioxidants, refine the oil, then pour that almost pure palmitic-rich fat into chips, biscuits, and frozen foods.
On a label this shows up as “vegetable oil (palm)” or just “palm oil”. On your tongue it shows up as perfect crispness and melt.
2. Palmitic Acid & the Names of Fats
Why does palm oil feel so good in crisps and chocolate coatings? A big part of it is palmitic acid — a 16-carbon saturated fatty acid (16:0) that:
- melts around body temperature,
- gives a creamy, lingering mouthfeel,
- stabilises texture so foods stay solid at room temperature but soften in your mouth.
Palmitic acid gets its name from palm oil (Elaeis guineensis), where it’s abundant. Once inside you, palmitate is not just neutral padding:
- in excess, it promotes ceramide formation (lipid signalling linked to insulin resistance),
- activates certain PKC pathways and hypothalamic inflammation,
- changes lipoprotein patterns, especially in low-fibre, low-polyphenol diets.
- Palmitic — from palm oil.
- Stearic — from Greek stear, “tallow”; found in beef fat and cocoa.
- Myristic — from Myristica fragrans, the nutmeg tree.
- Lauric — from Laurus nobilis (laurel); abundant in coconut and palm kernel oil.
- Oleic — from oleum, oil; characteristic of olive oil.
Palmitate has excellent mouthfeel. The shame is not its existence — it’s how much of it we can now concentrate and hide in foods that never had that chemistry in nature.
3. “Carbs Make You Fat” vs Thermodynamics of Storage
The meme says: “Carbs make you fat, not fat.” Biochemistry says: it’s easier to store fat as fat.
3.1 The Glycogen Sink & Thermic Effect
When you eat carbohydrate, several things happen before any of it can become body fat:
- Some burns immediately in brain, muscle, and organs.
- Some is stored as glycogen in liver and muscle, with water attached (about 3 g water per 1 g glycogen).
- Some is lost as heat via the thermic effect of food (~5–10% for carbs).
Only when glycogen stores are comfortably full and intake is chronically high does the body ramp up de novo lipogenesis (making fat from carbohydrate). That process:
- costs ATP,
- uses NADPH for chain elongation,
- loses perhaps 20–30% of the energy as heat in the conversion chain.
3.2 Fat: Direct Deposit
Dietary fat is already a long carbon chain. For the most part the body:
- packages it into chylomicrons,
- uses lipoprotein lipase to drop fatty acids into adipocytes,
- re-esterifies them into triglycerides.
Very little energy is lost in this process. Fat arrives as fat, stays as fat, at ~9 kcal/g (labelled 9, often approximated as 4 × 2+).
4. “But It’s Got Protein Though…”
Modern marketing loves protein. Protein bars, protein cookies, protein cereal, protein yoghurts. The implication: if it has protein, it’s healthful.
But humans don’t need “protein” as a logo. We need a pattern of amino acids that:
- maintains muscle and organs,
- doesn’t keep mTOR and IGF-1 signalling slammed on all day,
- arrives packaged with fibre, micronutrients, and low levels of oxidative stressors.
Many “high-protein” processed foods get their numbers by:
- adding isolated whey, casein, or collagen,
- keeping the sat fat + sugar + emulsifier matrix intact.
Protein blends heavy in certain amino acids (e.g. leucine, methionine) in a high-calorie, low-fibre environment can:
- push growth signals (mTOR, IGF-1) hard and often,
- in some contexts associate with higher risk of certain cancers, especially when paired with chronic inflammation and excess energy.
It’s not “protein = bad”. It’s what kind, how much, in what matrix, and for which body at which age.
5. Keto, Scale Drops, and Why Insulin Is Not the Villain
Very low-carb and keto diets often produce dramatic early scale changes. Some of that is:
- Glycogen depletion — each gram of glycogen carries several grams of water.
- Water loss from lowered insulin and natriuresis.
- Sometimes, loss of lean tissue if energy and training are not managed.
Insulin is often painted as pure evil. In reality it is:
- anabolic and anti-catabolic (helps preserve muscle),
- part of normal signalling that lets thyroid, sex hormones, and growth factors talk properly,
- a brake on excessive lipolysis (chronic runaway fat breakdown is not healthful either).
You can absolutely lose weight eating high-fat meals. The question for long-term health is: what else comes with that fat? Butter coffee, ribs, bacon grease, and beef tallow give energy and some protein — but almost no fibre, phytonutrients, or water. A very different signal than beans, lentils, whole grains, veg, fruit, and modest whole-food fats.
6. Labels, Loopholes & “Trade Secrets”
The front of the packet says “no trans fats”. The back says nothing obvious. But the ingredient list quietly includes:
- “Partially hydrogenated” oils in some regions,
- or the label uses rounding rules so that <x per serving becomes “0 g”.
In other cases, you don’t even get to know the exact chemistry:
- “Flavourings” and “spice mixes” protected as trade secrets.
- Acid regulators, anti-caking agents, and carriers that never make the front of pack.
7. Preservatives: Benzoate, Benzene & Potassium Sorbate
Preservatives exist for a reason: microbes love sugar water more than we do. But some combinations create chemistry we didn’t intend.
7.1 Sodium Benzoate + Vitamin C → Benzene
Sodium benzoate is a common preservative in acidic drinks. In the presence of:
- ascorbic acid (vitamin C),
- heat, light, trace metals,
benzoate can decarboxylate to form benzene, a known carcinogen.
In the 2000s, some soft drinks were found with benzene levels far above drinking water standards — sometimes many-fold higher exposure from a single can than from a day’s tap water. Regulations and formulations were updated, but the chemistry lesson remains: ingredients interact.
7.2 Potassium Sorbate & Friends
Potassium sorbate inhibits yeasts and moulds. On its own, at typical levels, it’s considered relatively safe. But its presence tells you something important: this food is designed to sit on a shelf for a long time — often a marker of ultra-processed, low-water, high-fat or high-sugar matrices.
8. Carrageenan, Emulsifiers & the Gut Barrier
Many products need water and fat to stay perfectly mixed for weeks or months:
- ice creams and desserts,
- coffee creamers,
- ready meals and sauces.
8.1 Carrageenan
Carrageenan is a sulphated polysaccharide from red seaweed, used as a thickener and stabiliser. In some animal and cell models, certain forms of carrageenan (especially degraded types) can:
- promote gut inflammation,
- disrupt tight junction proteins,
- exacerbate symptoms in sensitive individuals.
Not everyone reacts. But if your gut is already irritated, carrageenan can be one more straw on the camel’s back.
8.2 Emulsifiers & Gut Flora
Emulsifiers like polysorbate-80 and carboxymethylcellulose help fats and water stay blended. In mouse models and some human data, chronic exposure:
- thins the mucus layer that protects the gut wall,
- alters microbiome composition,
- can increase metabolic endotoxemia (more LPS slipping into circulation).
9. Powders, Dust & Surface Area
Another ultra-processed trick: take a whole food, pulverise it, and then rebuild it into something else.
- Milk → milk powder → used in chocolate, sauces, bakery fillings.
- Wheat → refined flour → expanded snacks and coatings.
- Starch → maltodextrin → cheap filler and texture agent.
Smaller particle size means:
- faster digestion and absorption,
- more surface for oxidation and Maillard reactions during processing,
- easier “hyper-palatable” blends with fat, sugar, and flavours.
10. Obesogens, Diabetogens, Excitation & Endotoxins
Beyond macros and named additives, a modern diet can carry quieter passengers:
- Obesogens — chemicals that nudge fat cells to store more or multiply (some plasticisers, pesticides).
- Diabetogens — exposures that worsen insulin sensitivity or β-cell stress.
- Excitatory signals — very high glutamate / aspartate doses plus other stressors can, in some contexts, over-stimulate neurons or appetite circuitry (separate from the old simplistic MSG panic).
- Endotoxins (LPS) — fragments from bacterial cell walls entering blood when gut barrier is leaky.
High-fat, low-fibre, emulsifier-rich meals, especially with alcohol or sleep deprivation, are the perfect storm: more chylomicrons, more endotoxin crossing, more low-grade inflammation simmering in the background.
11. The Egg, the Ovary & Hormones in Food
When you eat an egg, you’re eating the output of a metabolically active ovary — a cell factory that:
- packages fats, proteins, and micronutrients to fuel early development,
- relies on oestrogen and progesterone signalling to coordinate cycles.
The question is not “are hormones present?” (they’re also in plants, in different forms), but:
- how often,
- in what quantities,
- alongside what fat, fibre, and lifestyle environment?
12. Tesco Label Tour: Where the Fat Actually Hides
To make this concrete, you can pick any supermarket (Tesco, Sainsbury’s, etc.) and scan products like:
- “high-protein” cookies,
- ready-made garlic bread and cheesy flatbreads,
- “oven” chips and wedges,
- “healthy” granola clusters and snack bars.
• % calories from fat, sugar, protein.
• grams of saturated fat per 100 g.
• list of key additives (emulsifiers, preservatives, flavourings).
Underneath, paste the real Tesco ingredient list and highlight hidden fats and additives.
Example “High-Protein Cookie”
Front of pack: “15 g protein per serving”. Back of pack: palm oil, whey isolate, glucose syrup, flavourings, emulsifiers.
The protein halo pulls focus away from the core structure: refined flour + sugar + palm-rich fat + additives. The metabolic story is a dense, low-fibre, high-energy disc that melts into the bloodstream.
Example “Bake at Home” Garlic Bread
Looks like bread with herbs. Under the hood:
- white flour,
- palm oil and/or butter concentrate,
- emulsifiers to stop it leaking,
- maybe preservatives for a long chilled life.
Baked, it becomes a fat sponge: crisp outside, molten inside — palmitic mouthfeel in every bite.
13. Putting It Together: Holistic, Not Hopeless
None of this means you must never eat a cookie, fry, or slice of garlic bread again. The point is to see the whole system:
- Hidden fat is easier to store than most people realize.
- “But it’s got protein” doesn’t cancel out ultra-processing and sat-fat load.
- Additives, emulsifiers, and powders nudge gut and hormones in small but persistent ways.
- Carbs are not intrinsically “the enemy” — context, form, and movement decide their fate.
- Long-term health loves foods that are high-water, high-fibre, high-micronutrient, and minimally processed.
Food isn’t good or bad because of one number on the label. It’s the pattern — of molecules, meals, and years — that writes your story.
Sources & Further Reading
- Biochemistry & nutrition textbooks on fatty acid metabolism, de novo lipogenesis, and thermic effect of food.
- Literature on palmitic acid, ceramides, and hypothalamic inflammation.
- Regulatory and review documents on sodium benzoate, benzene formation, and preservative safety.
- Studies on emulsifiers (polysorbate-80, carboxymethylcellulose), mucus barrier, and microbiome alterations.
- Research on mTOR/IGF-1, amino acid patterns, and cancer/aging risk in different dietary contexts.